Abstract:
Nitrogen isotope compositions (δ¹⁵N values) of kerogen in the sedimentary rocks from the 1878 Ma Gunflint Formation were analysed to understand the relationships among microbial activities, ocean chemistry, and tectonic evolution in the Animikie Basin. In the present study, the stepwise combustion analysis, performed on 13 kerogen samples, indicates that the δ¹⁵N values of kerogen can be sub-divided into two fractions with discrete values depending on the combustion temperatures: a lower-temperature fraction (from 500 to 575 ˚C), and a higher-temperature fraction (higher than 575 ˚C). A positive correlation was observed between the δ¹⁵N values of the lower-temperature fractions and Pr/Sm ratios, which represent contributions from the continental input. In contrast, no correlation was observed between the δ¹⁵N values of the higher-temperature fractions and the Pr/Sm ratios. This relationship between the δ¹⁵N values and the continental inputs is explained by the isotopic fractionation effects of the biological nitrogen cycle associated with the enhanced microbial activity, triggered by the active tectonic settings in the Animikie basin.

Geochem. Persp. Let. (2017) 4, 13-18 | doi: 10.7185/geochemlet.1729 | Published 5 August 2017

Abstract:
Using Melt-PX to model the decompression melting of a heterogeneous mantle, I investigated the role of major-element composition of the lithologies present in the source on magmatic productivity, and trace element and isotopic melt compositions, independently of the bulk mantle composition. My calculations demonstrate that the volume of magma produced is not significantly affected by the nature of the lithological heterogeneity, but depends on the bulk mantle composition. However, an isochemical bulk mantle can produce contrasting trace element and isotopic melt compositions depending on the major-element compositions of the lithologies present in the source. Results show that the observed crust thickness of the Icelandic rift zones is consistent with about 10 % of recycled crust in the source, but also demonstrate there is no need to involve the contribution of melts derived from a recycled basalt component to explain the compositional variability of the Icelandic basalts in rift zones, and rather advance the contribution of olivine-bearing hybrid lithologies formed by solid-state reactions between the recycled crust and the peridotite.

Geochem. Persp. Let. (2017) 4, 7-12 | doi: 10.7185/geochemlet.1728 | Published 12 July 2017

Abstract:
Metasomatism, the chemical alteration of rocks by a variety of melts and fluids, has formed a key concept in studies of the Earth’s mantle for decades. Metasomatic effects are often inferred to be far-reaching and yet the evidence for their occurrence is usually based upon individual hand specimens or suites of rocks that display considerable heterogeneity. In rare cases, however, we are offered insights into larger-scale chemical modifications that occur in the mantle. Here we utilise the Lu–Hf systematics of zircon megacrysts erupted in kimberlite magmas to discern two temporally and compositionally discrete metasomatic events in the mantle beneath southern Africa, each having an influence extending over an area exceeding one million km². These data provide unambiguous evidence for metasomatic processes operating at continental scales and seemingly unperturbed by the age and composition of the local lithospheric mantle. The most recent of these events may be associated with the major Jurassic-Karoo magmatism in southern Africa.

Geochem. Persp. Let. (2017) 4, 1-6 | doi: 10.7185/geochemlet.1727 | Published 10 July 2017

Abstract:
Chemical weathering of silicate rocks is a primary drawdown mechanism of atmospheric carbon dioxide. The processes that affect weathering are therefore central in controlling global climate. A temperature-controlled “weathering thermostat” has long been proposed in stabilising long-term climate, but without definitive evidence from the geologic record. Here we use lithium isotopes (δ⁷Li) to assess the impact of silicate weathering across a significant climate-cooling period, the end-Ordovician Hirnantian glaciation (~445 Ma). We find a positive δ⁷Li excursion, suggestive of a silicate weathering decline. Using a coupled lithium-carbon model, we show that initiation of the glaciation was likely caused by declining CO₂ degassing, which triggered abrupt global cooling, and much lower weathering rates. This lower CO₂ drawdown during the glaciation allowed climatic recovery and deglaciation. Combined, the data and model provide support from the geological record for the operation of the weathering thermostat.

Geochem. Persp. Let. (2017) 3, 230-237 | doi: 10.7185/geochemlet.1726 | Published 15 June 2017

Abstract:
The Poll a’Mhuilt Member of the Stoer Group (Torridonian Supergroup) in Scotland has been heralded as a rare window into the ecology of Mesoproterozoic terrestrial environments. Its unusually high molybdenum concentrations and large sulphur isotope fractionations have been used as evidence to suggest that lakes 1.2 billion years ago were better oxygenated and enriched in key nutrients relative to contemporaneous oceans, making them ideal habitats for the evolution of eukaryotes. Here we show with new Sr and Mo isotope data, supported by sedimentological evidence, that the depositional setting of this unit was likely connected to the ocean and that the elevated Mo and S contents can be explained by evapo-concentration of seawater. Thus, it remains unresolved if Mesoproterozoic lakes were important habitats for early eukaryotic life.

Geochem. Persp. Let. (2017) 3, 221-229 | doi: 10.7185/geochemlet.1725 | Published 13 June 2017

Abstract:
The Phanerozoic radiation of bilaterian animals has been linked to oxygenation of Earth's oceans, due to the oxygen demand of the evolving animal ecosystems. However, how early animals may have regulated Earth’s surface oxygen budget via self-stabilising feedbacks is poorly understood. Here, we report parallel positive uranium, carbon, and sulphur isotope excursions from carbonate successions in Siberia that document a brief global oxygenation episode 521–520 Myr ago, at the onset of diversification of larger arthropods known from the fossil record. Our data and model indicate that an abrupt increase in the sinking rate of marine organic matter expanded the oxygenated zone in the oceans and that reducing conditions returned 1.3 ± 0.8 Myr after the onset of this transient oxygenation episode, necessitating a strong negative feedback to the increasing levels of oxygen. We speculate that larger zooplankton could have sourced both oxygen and food to the seafloor, fueling bioturbation over wider areas and, thereby, stabilising O₂-rich habitats in the oceans. Thus, this reorganisation exemplifies how animal ecosystems might have influenced oxygen availability in Earth's surface environment soon after their establishment.

Geochem. Persp. Let. (2017) 3, 210-220 | doi: 10.7185/geochemlet.1724 | Published 15 June 2017

Abstract:
The micronutrient iron (Fe) can be transported from marine terminating glaciers to the ocean by icebergs. There are however few observations of iceberg Fe content, and the flux of Fe from icebergs to the offshore surface ocean is poorly constrained. Here we report the dissolved Fe (DFe), total dissolvable Fe (TdFe) and ascorbic acid extractable Fe (FeAsc) sediment content of icebergs from Kongsfjorden, Svalbard. The concentrations of DFe (range 0.63 nM – 536 nM, mean 37 nM, median 6.5 nM) and TdFe (range 46 nM – 57 µM, mean 3.6 µM, median 144 nM) both demonstrated highly heterogeneous distributions and there was no significant correlation between these two fractions. FeAsc (range 0.0042 to 0.12 wt. %) was low compared to both previous measurements in Kongsfjorden and to current estimates of the global mean. FeAsc content per volume ice did however, as expected, show a significant relationship with sediment loading (which ranged from < 0.1 – 234 g L^-1 of meltwater). In the Arctic, icebergs lose their sediment load faster than ice volume due to the rapid loss of basal ice after calving. We therefore suggest that the loss of basal ice is a potent mechanism for the reduction of mean TdFe and FeAsc per volume of iceberg. Delivery of TdFe and FeAsc to the ocean is thereby biased towards coastal waters where, in Kongsfjorden, DFe (18 ± 17 nM) and TdFe (mean 8.1 µM, median 3.7 µM) concentrations were already elevated.

Geochem. Persp. Let. (2017) 3, 200-209 | doi: 10.7185/geochemlet.1723 | Published 7 June 2017

Abstract:
Mixing and juxtaposition of chemically distinct magmatic systems are key processes for the evolution of Earth’s crust. Yet, the physicochemical nature at mixing interfaces remains poorly described, as crystallisation, melting, heat transfer, and diffusion are interconnected and lead to complex mass transfer processes driving unique patterns of element fractionation. Here, we use diffusion couple experiments between felsic and mafic magmas (melt + crystals ± volatiles) to document the formation of large gradients in oxygen fugacity at the magma-magma mixing interface. Reducing and oxidising boundary layers at the interface develop rapidly and remain in dynamic disequilibrium for days to possibly weeks. We suggest that the observed transient redox gradient is caused by cation transfer across the interface where the required counter flux of electron holes is insufficient to compensate an evolving electron hole gradient. Such boundary layer redox effects may control fractionation of polyvalent and chalcophile elements and moderate, for example, Cu/Au ratios in arc-related porphyry ore deposits.

Geochem. Persp. Let. (2017) 3, 190-199 | doi: 10.7185/geochemlet.1722 | Published 15 May 2017

Abstract:
Zircon is the preeminent chronometer of deep time on Earth, informing models of crustal growth and providing our only direct window into the Hadean Eon. However, the quantity of zircon crystallised per unit mass of magma is highly variable, complicating interpretation of the terrestrial zircon record. Here we combine zircon saturation simulations with a dataset of ∼52,000 igneous whole rock geochemical analyses to quantify secular variation in relative zircon abundance throughout Earth history. We find dramatically increasing zircon abundance per mass of magma through geologic time, suggesting that the zircon record underestimates past crustal volume even if preservation bias is eliminated. Similarly, zircons were even less likely to crystallise from low-silica magmas in early Earth history than they are today, together suggesting that the observed Hadean zircon record may require a larger volume of generally felsic Hadean crust than previously expected.

Geochem. Persp. Let. (2017) 3, 179-189 | doi: 10.7185/geochemlet.1721 | Published 20 April 2017

Abstract:
The isotopic similarity of enstatite chondrites and Earth has often been cited as evidence that the Earth is made of enstatite chondrite-like material. Here we show, however, that enstatite chondrites exhibit nucleosynthetic molybdenum (Mo) isotope anomalies and, therefore, cannot represent the sole building blocks of the Earth. Enstatite and ordinary chondrites together with the Earth’s mantle plot on a cosmic Mo-Nd isotope correlation line that reflects varying proportions of s-process matter in these samples. This correlation indicates that the nucleosynthetic makeup of Earth’s building material did not change over time and that Earth, on average, accreted from bodies that originated closer to the Sun and were enriched in s-process matter compared to known chondrites. As such, any contribution of chondrites to Earth’s accreting material must be compensated by the addition of s-process enriched bodies. This material is not present in our meteorite collections, but may have been sampled by Venus or Mercury. The s-process enriched nature of the Earth can fully account for its higher ¹⁴²Nd compared to chondrites, which therefore does not require an early differentiation of Earth’s mantle.

Geochem. Persp. Let. (2017) 3, 170-178 | doi: 10.7185/geochemlet.1720 | Published 14 April 2017

Abstract:
Subduction zones are the sites where crustal materials are recycled into the mantle. In response to increasing pressures and temperatures during this process, hydrated minerals break down and release solute-bearing fluids and, above ~750 ˚C, form hydrous melts. Magmas generated by interaction of these melts and fluids with the mantle have a characteristic arc elemental signature. Here, a zoned refractory tourmaline grain, formed during Alpine subduction and uplift, was used to reconstruct the compositions of the fluids involved in element transfer. The reconstructed compositions confirm that slab-released fluids carry the arc-signa­ture, and suggest that mineral–fluid element partitioning controls their compositions. However, these fluids are calculated to be dilute. To reconcile this with higher element-to-water ratios required for arc magmas, a two-stage arc-magma genesis model is favoured where fluids imprint their compositional signature progressively on a slab mélange that is subsequently trans­fer­red to, and interacts with the mantle to generate arc magmas.

Geochem. Persp. Let. (2017) 3, 160-169 | doi: 10.7185/geochemlet.1719 | Published 28 March 2017

Abstract:
The isotopic and elemental compositions of noble gases constitute a powerful tool to study volatile origin and evolution, due to their inertness, and can thus provide crucial information about the early stage of planetary formation. Two models are proposed to explain the light noble gas origin on Earth: the solar wind implantation model and the solar nebula gas dissolution model. However, noble gas measurements often show addition of air to the mantle-derived gas, which complicates the determination of mantle isotopic ratios. We analysed the noble gas isotopic compositions of single vesicles in samples from the Galápagos hotspot with laser ablation, in order to understand and remove this atmospheric component, as well as discriminate between the two scenarios. Based on the new high precision results and a new statistical approach, we show that the solar wind implantation model is more likely to explain the terrestrial He, Ne and Ar composition. This scenario could bring important constraints on the solar system environment during the early stage of planetary formation.

Geochem. Persp. Let. (2017) 3, 151-159 | doi: 10.7185/geochemlet.1718 | Published 13 March 2017

Abstract:
Alzheimer’s disease is associated with abnormal homeostasis of Zn, because of deposits of Zn-rich amyloid-β fibrils. This connection between Zn and brain aging provides a possibility to use changes in Zn homeostasis to study the evolution of the disease. Here, we studied the evolution of the Zn isotopic composition of brain, serum and red blood cells from APPswe/PSEN1dE9 transgenic mice, which develop Alzheimer’s-like disease (including Aβ deposition starting after 6 months), in comparison to wild type controls. We found that wild type brains become progressively enriched in the lighter isotopes of Zn between 6 and 12 months. We interpret this enrichment in terms of changes in Zn speciation in the cytoplasm, where isotopically heavy unbound Zn²⁺ is bound to glutamate released by presynaptic vesicles of neurons. Brains from APPswe/PSEN1dE9 mice were enriched in the heavier isotopes of Zn when compared to wild type suggesting an increase in Zn content of the brain associated with Aβ plaques where Zn binds preferentially to isotopically heavy amino acids such as histidine and glutamate.

Geochem. Persp. Let. (2017) 3, 142-150 | doi: 10.7185/geochemlet.1717 | Published 15 March 2017

Comment on “A cometary origin for atmospheric martian methane” by Fries et al., 2016:
Reports of transient plumes of martian atmospheric methane (Mumma et al., 2009; Webster et al., 2015) have led to suggestions of biologic or abiotic surface sources. Schuerger et al. (2012) examined the production of methane near the surface from interplanetary dust particles. They found this mechanism was capable of yielding the background value of methane, but could not reproduce plume densities by bolide, airburst or other meteor impact process. Fries et al. (2016) draw on the work of Schuerger et al. (2012) and propose that the methane plumes are sourced instead from intense meteor showers with conversion at high altitudes.

Geochem. Persp. Let. (2017) 3 | doi: 10.7185/geochemlet.1715 | Published 18 February 2017

Reply to Comment on “A cometary origin for martian atmospheric methane”
by Crismani et al., 2017:
First, I would like to extend thanks to Crismani et al. for their commentary, which highlights an important uncertainty acknowledged in Fries et al. (2016), namely whether the total mass of infall material required to produce the observed methane is on par with that available from meteor showers. I would like to disagree on two points presented in the letter, and then discuss the implications of their findings.

Geochem. Persp. Let. (2017) 3 | doi: 10.7185/geochemlet.1716 | Published 18 February 2017