Fast REE re-distribution in mantle clinopyroxene via reactive melt infiltration
Affiliations | Corresponding Author | Cite as | Funding information- Share this article
-
Article views:604Cumulative count of HTML views and PDF downloads.
- Download Citation
- Rights & Permissions
top
Abstract
Figures
Figure 1 (a) Map of Ca distribution in the whole capsule after reaction experiments on Basalt:Clinopyroxene:Olivine (BCO) 1:1:1, at 1.5 GPa and 1300 °C; red areas (high Ca) depict relicts of starting clinopyroxene. (b) Phase map derived by combining X-ray concentration maps (Ca, Mg, Al). (c) Backscattered electron (BSE) image and Ca map showing details of Ca-rich relict clinopyroxene that is partially substituted by rims of new crystallised clinopyroxene. (d) New cpx/relict cpx ratio (i.e. clinopyroxene textural replacement) versus run duration of experiments (time, hours). (e) Ca (a.p.f.u.) versus XMg value [Mg/(Mg + Fetot)] of starting, new and relict clinopyroxenes in reaction experiments; also shown is the composition of clynopyroxene in equilibrium crystallisation experiments at 2 GPa and 1300 °C. (f) Chondrite normalized REE patterns of average clinopyroxene in reaction and crystallisation experiments compared to the average REE pattern of starting clinopyroxene; grey field is defined by REE patterns of relict clinopyroxenes. | Figure 2 Chondrite normalised (a) LaN/SmN versus YbN and (b) SmN/NdN versus LuN/HfN of initial, new and relict clinopyroxene from reacted and crystallisation experiments compared to data of clinopyroxenes in metasomatised peridotites from Northern Apennine veined mantle (black diamonds, Borghini et al., 2020). | Figure 3 “Reaction” DREEcpx/melt from this study compared to (a) DREEcpx/melt derived by equilibrium crystallisation experiment at 2 GPa and 1300 °C and those from the literature (list of references is in the text), and (b) the DREEcpx/melt provided by the application of the parameterised lattice strain model by Sun and Liang (2012), to each reaction experiments of this study. |
Figure 1 | Figure 2 | Figure 3 |
top
Introduction
Porous flow is the main mechanism of melt transport in the deep hot mantle and within the thermal boundary layer. Reaction between mantle minerals and transient melts may strongly affect the mineralogy and chemistry of the upper mantle (e.g., Rampone et al., 2020
Rampone, E., Borghini, G., Basch, V. (2020) Melt migration and melt-rock reaction in the Alpine-Apennine peridotites: Insights on mantle dynamics in extending lithosphere. Geoscience Frontiers 11, 151–166. https://doi.org/10.1016/j.gsf.2018.11.001
, and references therein). Modal and chemical changes in mantle peridotite can occur as a result of diffuse porous flow, or by focused melt infiltration related to melt-bearing conduits (dunite channels), or pyroxenitic veins and layers (mantle re-fertilization; e.g., Warren, 2016Warren, J.M. (2016) Global variations in abyssal peridotite compositions. Lithos 248–251, 193–219. http://dx.doi.org/10.1016/j.lithos.2015.12.023
). Melt-rock reactions are therefore able to modify large portions of the mantle and create chemical and isotopic heterogeneity at different length scales and geological settings.Changes in mineral abundances and chemistry are mainly controlled by physical parameters, as well as the composition and amount (i.e. the melt-rock ratio) of the reacting melt. The interaction between an infiltrating melt and partially molten peridotite is controlled by grain-scale processes that involve dissolution, precipitation, reprecipitation and diffusive exchange between the interstitial melt and surrounding crystals (Liang, 2003
Liang, Y. (2003) Kinetics of crystal-melt reaction in partially molten silicates: 1. Grain scale processes. Geochemistry, Geophysics, Geosystems 4, 1045. https://doi.org/10.1029/2002GC000375
). Several numerical and theoretical studies investigated the role and kinetics of these grain-scale processes (e.g., Navon and Stolper, 1987Navon, O., Stolper, E. (1987) Geochemical Consequences of Melt Percolation: The Upper Mantle as a Chromatographic Column. The Journal of Geology 95, 285–307. https://doi.org/10.1086/629131
; Hauri, 1997Hauri, E.H. (1997) Melt migration and mantle chromatography, 1: simplified theory and conditions for chemical and isotopic decoupling. Earth and Planetary Science Letters 153, 1–19. https://doi.org/10.1016/S0012-821X(97)00157-X
; Van Orman et al., 2002Van Orman, J.A., Grove, T.L., Shimizu, N. (2002) Diffusive fractionation of trace elements during production and transport of melt in Earth’s upper mantle. Earth and Planetary Science Letters 198, 93–112. https://doi.org/10.1016/S0012-821X(02)00492-2
) and laboratory experiments successfully reproduced textural and chemical variations observed in natural mantle samples (e.g., Morgan and Liang, 2005Morgan, Z., Liang, Y. (2005) An experimental study of the kinetics of lherzolite reactive dissolution with applications to melt channel formation. Contributions to Mineralogy and Petrology 150, 369–385. https://doi.org/10.1007/s00410-005-0033-8
; Van den Bleeken et al., 2010Van Den Bleeken, G., Müntener, O., Ulmer, P. (2010) Reaction Processes between Tholeiitic Melt and Residual Peridotite in the Uppermost Mantle: an Experimental Study at 0.8 GPa. Journal of Petrology 51, 153–183. https://doi.org/10.1093/petrology/egp066
; Wang et al., 2020Wang, C., Lo Cascio, M., Liang, Y., Xu, W. (2020) An experimental study of peridotite dissolution in eclogite-derived melts: Implications for styles of melt-rock interaction in lithospheric mantle beneath the North China Craton. Geochimica et Cosmochimica Acta 278, 157–176. https://doi.org/10.1016/j.gca.2019.09.022
). However, very few experimental studies have directly investigated the trace element (re-)distribution in mantle minerals resulting from melt-peridotite reaction (Lo Cascio et al., 2008Lo Cascio, M., Liang, Y., Shimizu, N., Hess, P.C. (2008) An experimental study of the grain-scale processes of peridotite melting: implications for major and trace element distribution during equilibrium and disequilibrium melting. Contributions to Mineralogy and Petrology 156, 87–102. https://doi.org/10.1007/s00410-007-0275-8
; Yao et al., 2012Yao, L., Sun, C., Liang, Y. (2012) A parameterized model for REE distribution between low-Ca pyroxene and basaltic melts with applications to REE partitioning in low-Ca pyroxene along a mantle adiabat and during pyroxenite-derived melt and peridotite interaction. Contributions to Mineralogy and Petrology 164, 261–280. https://doi.org/10.1007/s00410-012-0737-5
; Ma and Shaw, 2021Ma, S., Shaw, C.S.J. (2021) An Experimental Study of Trace Element Partitioning between Peridotite Minerals and Alkaline Basaltic Melts at 1250°C and 1 GPa: Crystal and Melt Composition Impacts on Partition Coefficients. Journal of Petrology 62, egab084. https://doi.org/10.1093/petrology/egab084
) which is mostly due to analytical difficulties in measuring trace element concentrations of fine-grained experimental phases. In particular, the efficiency of melt-rock reaction in modifying or resetting the trace element composition of mantle clinopyroxene, which is the main trace element carrier in spinel peridotites (about 1–2 GPa), still remains to be experimentally evaluated.We performed high pressure reaction experiments at 1–2 GPa, 1200–1350 °C, on homogeneous mixtures of clinopyroxene (250–160 μm), olivine and an enriched MORB melt (Table S-1 and Fig. S-1; full description of experimental details in Supplementary Information). Initial weight proportions among basalt, clinopyroxene and olivine are 1:1:1, except for one run performed with a mix of 2:1:1, respectively (Table S-2). Such a high melt/rock ratio is consistent with previous melt transport experiments (e.g., Lambart et al., 2009
Lambart, S., Laporte, D., Schiano, P. (2009) An experimental study of focused magma transport and basalt–peridotite interactions beneath mid-ocean ridges: implications for the generation of primitive MORB compositions. Contributions to Mineralogy and Petrology 157, 429–451. https://doi.org/10.1007/s00410-008-0344-7
) or melt-peridotite interaction occurring in the host mantle of pyroxenite veins (Bodinier et al., 2004Bodinier, J.-L., Menzies, M.A., Shimizu, N., Frey, F.A., McPherson, E. (2004) Silicate, Hydrous and Carbonate Metasomatism at Lherz, France: Contemporaneous Derivatives of Silicate Melt–Harzburgite Reaction. Journal of Petrology 45, 299–320. https://doi.org/10.1093/petrology/egg107
). Adopting a simplified mantle assemblage (olivine +clinopyroxene) promoted the development of coarse textures suitable for the analysis of the trace element composition with laser ablation ICP-MS techniques. Here we experimentally determine textural and chemical effects of reactive infiltration/migration of REE-enriched melt within a mantle peridotite with particular focus on REE re-distribution via melt-clinopyroxene interaction at asthenosphere-lithosphere conditions.top
Melt-Peridotite Reaction Experiments
All experiments produced chemical and textural evidence of the reaction melt1 + cpx1 + ol1 = melt2 + cpx2 + ol2, implying the dissolution and recrystallisation of olivine and clinopyroxene (Table S-2). Accordingly, at 1–2 GPa clinopyroxene is the liquidus phase for the selected basaltic glass (Fig. S-2). In the long duration runs (≥48 h), olivine has rather homogeneous major element compositions marked by higher CaO and lower NiO and XMg [XMg = Mg/(Mg + Fetot)] than the initial SC olivine (Fig. S-3), as observed in basalt-dunite reaction experiments (Borghini et al., 2018
Borghini, G., Francomme, J.E., Fumagalli, P. (2018) Melt-dunite interactions at 0.5 and 0.7 GPa: experimental constraints on the origin of olivine-rich troctolites. Lithos 323, 44–57. https://doi.org/10.1016/j.lithos.2018.09.022
). New crystallised clinopyroxene has partially replaced the starting clinopyroxene forming rims on initial clinopyroxene relics or homogeneous grains precipitated by the reacted melt (Fig. 1a, c). New clinopyroxenes have lower Ca and Cr contents and higher Na concentrations with respect to the initial clinopyroxene (Fig. S-2, Tables S-3 and S-4). By contrast, most clinopyroxene relics preserve the initial major element composition (Fig. 1, Tables S-3 and S-4). AlIV content in clinopyroxene varies within a rather narrow range in a single experiment and tends to be higher in the runs with a high degree of crystallisation or a higher initial melt proportion (Fig. S-3). Reacted glasses still retain basaltic major element compositions but exhibit higher XMg than the initial basalt (Table S-6) due to reaction with mantle phases.Image analysis, derived by combining X-ray concentration maps, provided estimates of modal variations caused by the reaction (Figs. 1b, S-2 and Table S-2). The degree of clinopyroxene textural replacement (new cpx/relict cpx ratio) increases with temperature and run duration (Fig. 1d). At 1.5 GPa, 1300 °C, and 2 GPa, 1350 °C, clinopyroxene is almost completely renewed by reaction with the melt, in runs of 69 and 48 hours, respectively. The extent of reacted melt crystallisation in experiments increases with increasing pressure and/or decreasing temperature, as demonstrated by the low final melt/rock ratio in experiment at 2 GPa and 1300 °C (Table S1 and Fig. S-2).
top
REE Distribution after Melt-Cpx Interaction
Consistent with the fast diffusion in silicate melt, experimental glasses have homogeneous trace element concentrations, and show LREE-HREE fractionation (LaN/YbN = 1.74–3.66) slightly lower than the initial glass (LaN/YbN = 5.49), mostly reflecting the dissolution of LREE-depleted clinopyroxene (Table S-9). Compared to the starting clinopyroxene, the new clinopyroxenes show REE patterns characterised by a systematic lowering of HREE and MREE and increasing fractionation of LREE over the MREE reflecting the crystallisation from enriched reacted melts (Fig. 1f). Remarkably, relict clinopyroxenes are modified; the slight but systematic LREE (and Sm) enrichment compared to the starting clinopyroxene (Fig. 1f) reflects partial REE re-equilibration via diffusion presumably driven by the more pronounced difference in LREE concentration between initial clinopyroxene and melt, at rather close HREE abundances. REE diffusion within cpx relics coincides with dissolution and precipitation during the interaction with melts (Lo Cascio et al., 2008
Lo Cascio, M., Liang, Y., Shimizu, N., Hess, P.C. (2008) An experimental study of the grain-scale processes of peridotite melting: implications for major and trace element distribution during equilibrium and disequilibrium melting. Contributions to Mineralogy and Petrology 156, 87–102. https://doi.org/10.1007/s00410-007-0275-8
). Theoretical studies revealed that REE fractionation via diffusion is rather sluggish during melt porous flow (e.g., Van Orman et al., 2002Van Orman, J.A., Grove, T.L., Shimizu, N. (2002) Diffusive fractionation of trace elements during production and transport of melt in Earth’s upper mantle. Earth and Planetary Science Letters 198, 93–112. https://doi.org/10.1016/S0012-821X(02)00492-2
; Liang, 2003Liang, Y. (2003) Kinetics of crystal-melt reaction in partially molten silicates: 1. Grain scale processes. Geochemistry, Geophysics, Geosystems 4, 1045. https://doi.org/10.1029/2002GC000375
). However, REE diffusion over a distance of less than 200 μm has been observed in reaction couple experiments (Lo Cascio et al., 2008Lo Cascio, M., Liang, Y., Shimizu, N., Hess, P.C. (2008) An experimental study of the grain-scale processes of peridotite melting: implications for major and trace element distribution during equilibrium and disequilibrium melting. Contributions to Mineralogy and Petrology 156, 87–102. https://doi.org/10.1007/s00410-007-0275-8
). In our experimental setup both dissolution and reprecipitation and solid-liquid REE diffusion into the relict clinopyroxenes occur, thus resulting in the whole chemical modification of the initial mantle clinopyroxene at sizes lower than 250 μm, along 2–3 day experiments. These results indicate that rapid textural replacement of relict clinopyroxene strongly improves trace element remobilisation, even for LREE having low diffusion rate (Van Orman et al., 2001Van Orman, J.A., Grove, T.L., Shimizu, N. (2001) Rare earth element diffusion in diopside: influence of temperature, pressure, and ionic radius, and an elastic model for diffusion in silicates. Contributions to Mineralogy and Petrology 141, 687–703. https://doi.org/10.1007/s004100100269
).New clinopyroxenes show clockwise-rotated average REE patterns (Fig. 1f), very similar to REE patterns computed in studies that documented the effect of interaction between enriched melts and residual clinopyroxene within pyroxenite-bearing veined peridotite (Borghini et al., 2020
Borghini, G., Rampone, E., Zanetti, A., Class, C., Fumagalli, P., Godard, M. (2020) Ligurian pyroxenite-peridotite sequences (Italy) and the role of melt-rock reaction in creating enriched-MORB mantle sources. Chemical Geology 532, 119252. https://doi.org/10.1016/j.chemgeo.2019.07.027
), or during melt infiltration during open system mantle melting, to explain the trace element variability of abyssal peridotite (Brunelli et al., 2014Brunelli, D., Paganelli, E., Seyler, M. (2014) Percolation of enriched melts during incremental open-system melting in the spinel field: A REE approach to abyssal peridotites from the Southwest Indian Ridge. Geochimica et Cosmochimica Acta 127, 190–203. https://doi.org/10.1016/j.gca.2013.11.040
). We found that the fractionation of LREE over the MREE varies as a function of experimental conditions. In particular, clinopyroxenes in experiments that experienced the highest extent of reacted melt crystallisation at 2 GPa and 1300 °C (Fig. 2a) exhibit high LaN/SmN ratios (LaN/SmN = 0.42–0.56), reflecting REE fractionation of crystallising reacted melt. Moreover, high LaN/SmN ratios in new clinopyroxenes have been found in the reaction experiment with a higher amount of starting basalt. Similar high LaN/SmN ratios have been documented in mantle peridotites inferred to be metasomatised by E-MORB-like melts coming from pyroxenitic veins (Northern Apennine veined mantle; Borghini et al., 2020Borghini, G., Rampone, E., Zanetti, A., Class, C., Fumagalli, P., Godard, M. (2020) Ligurian pyroxenite-peridotite sequences (Italy) and the role of melt-rock reaction in creating enriched-MORB mantle sources. Chemical Geology 532, 119252. https://doi.org/10.1016/j.chemgeo.2019.07.027
). Ancient events of melt infiltration in those peridotites modified the trace element composition of clinopyroxene by lowering SmN/NdN and LuN/HfN ratios that, over time, formed mantle domains with enriched Nd-Hf isotopic signatures (Borghini et al., 2021Borghini, G., Rampone, E., Class, C., Goldstein, S., Cai, Y., Cipriani, A., Hofmann, A.W., Bolge, L. (2021) Enriched Hf–Nd isotopic signature of veined pyroxenite-infiltrated peridotite as a possible source for E-MORB. Chemical Geology 586, 120591. https://doi.org/10.1016/j.chemgeo.2021.120591
). Our experimental results show that high pressure and temperature interaction with E-MORB-type basalt causes rapid decrease of SmN/NdN and LuN/HfN ratios in newly formed clinopyroxene relative to the starting composition (Fig. 2b). In addition, diffusion combined with dissolution and reprecipitation results in variable but systematic chemical changes in clinopyroxene relics, again towards lower SmN/NdN and LuN/HfN ratios (Fig. 2b).Using the REE concentrations measured in new clinopyroxenes and texturally associated glasses, we computed “reaction” cpx/melt distribution coefficients (Fig. 3a), which are comparable to those derived by equilibrium experiments (Hart and Dunn, 1993
Hart, S.R., Dunn, T. (1993) Experimental cpx/melt partitioning of 24 trace elements. Contributions to Mineralogy and Petrology 113, 1–8. https://doi.org/10.1007/BF00320827
; Blundy et al., 1998Blundy, J.D., Robinson, J.A.C., Wood, B.J. (1998) Heavy REE are compatible in clinopyroxene on the spinel lherzolite solidus. Earth and Planetary Science Letters 160, 493–504. https://doi.org/10.1016/S0012-821X(98)00106-X
; Lundstrom et al., 1998Lundstrom, C.C., Shaw, H.F., Ryerson, F.J., Williams, Q., Gill, J. (1998) Crystal chemical control of clinopyroxene-melt partitioning in the Di-Ab-An system: implications for elemental fractionations in the depleted mantle. Geochimimica et Cosmochimica Acta 62, 2849–2862. https://doi.org/10.1016/S0016-7037(98)00197-5
; Hill et al., 2000Hill, E., Wood, B.J., Blundy, J.D. (2000) The effect of Ca-Tschermaks component on trace element partitioning between clinopyroxene and silicate melt. Lithos 53, 203–215. https://doi.org/10.1016/S0024-4937(00)00025-6
; McDade et al., 2003McDade, P., Blundy, J.D., Wood, B.J. (2003) Trace element partitioning on the Tinaquillo Lherzolite solidus at 1.5 GPa. Physics of the Earth and Planetary Interiors 139, 129–147. https://doi.org/10.1016/S0031-9201(03)00149-3
). These also closely overlap the equilibrium distribution coefficients measured for REE in our crystallisation run at 2 GPa and 1300 °C and those computed using parameterisation by Sun and LiangSun, C., Liang, Y. (2012) Distribution of REE between clinopyroxene and basaltic melt along a mantle adiabat: effects of major element composition, water, and temperature. Contributions to Mineralogy and Petrology 163, 807–823. https://doi.org/10.1007/s00410-011-0700-x
(2012Sun, C., Liang, Y. (2012) Distribution of REE between clinopyroxene and basaltic melt along a mantle adiabat: effects of major element composition, water, and temperature. Contributions to Mineralogy and Petrology 163, 807–823. https://doi.org/10.1007/s00410-011-0700-x
) based on the composition of clinopyroxenes in our reaction experiments (Fig. 3b). This suggests that new clinopyroxenes and reacted melt approached the chemical equilibrium even at the time scale of the experiment. These experiments reveal that small (<250 μm) mantle clinopyroxene is rapidly modified by a single step of interaction with a REE-enriched transient melt. In a scenario of multiple melt injections, porous migration of melts enriched in trace elements may efficiently refertilise mantle clinopyroxene (e.g., Brunelli et al., 2014Brunelli, D., Paganelli, E., Seyler, M. (2014) Percolation of enriched melts during incremental open-system melting in the spinel field: A REE approach to abyssal peridotites from the Southwest Indian Ridge. Geochimica et Cosmochimica Acta 127, 190–203. https://doi.org/10.1016/j.gca.2013.11.040
). Several interactions with REE-depleted clinopyroxene are expected to progressively smooth the LREE-HREE fractionation of a single batch of transient melt, as found in reacted glasses of this study, confirming the important role of melt transport processes in the chemical variations of erupted basalts (Navon and Stolper, 1987Navon, O., Stolper, E. (1987) Geochemical Consequences of Melt Percolation: The Upper Mantle as a Chromatographic Column. The Journal of Geology 95, 285–307. https://doi.org/10.1086/629131
).top
Conclusions
New experimental results demonstrate that melt-peridotite reaction is efficient in modifying the REE signature of mantle clinopyroxene by a combination of dissolution, precipitation and trace element diffusion. High reaction rate leads to local chemical equilibrium between clinopyroxene and melt even at the time scale of the experiments. These data demonstrate that infiltration of REE-enriched melt within a mantle peridotite is potentially able to completely reset the pristine trace element budget of clinopyroxene.
top
Acknowledgements
We thank two anonymous reviewers for constructive reviews and Anat Shahar for editorial handling. We greatly thank A. Cipriani for providing the starting basaltic glass. A. Risplendente and G. Sessa are thanked for technical assistance during the work at the electron microprobe and LA-ICP-MS, respectively, at University of Milano. Our thanks also go to B. Schmitte at the University of Münster for her excellent support during the LA-ICP-MS analyses that were done in the midst of the international Covid19 pandemic.
Editor: Anat Shahar
top
References
Blundy, J.D., Robinson, J.A.C., Wood, B.J. (1998) Heavy REE are compatible in clinopyroxene on the spinel lherzolite solidus. Earth and Planetary Science Letters 160, 493–504. https://doi.org/10.1016/S0012-821X(98)00106-X
Show in context
Using the REE concentrations measured in new clinopyroxenes and texturally associated glasses, we computed “reaction” cpx/melt distribution coefficients (Fig. 3a), which are comparable to those derived by equilibrium experiments (Hart and Dunn, 1993; Blundy et al., 1998; Lundstrom et al., 1998; Hill et al., 2000; McDade et al., 2003).
View in article
Bodinier, J.-L., Menzies, M.A., Shimizu, N., Frey, F.A., McPherson, E. (2004) Silicate, Hydrous and Carbonate Metasomatism at Lherz, France: Contemporaneous Derivatives of Silicate Melt–Harzburgite Reaction. Journal of Petrology 45, 299–320. https://doi.org/10.1093/petrology/egg107
Show in context
Such a high melt/rock ratio is consistent with previous melt transport experiments (e.g., Lambart et al., 2009) or melt-peridotite interaction occurring in the host mantle of pyroxenite veins (Bodinier et al., 2004).
View in article
Borghini, G., Francomme, J.E., Fumagalli, P. (2018) Melt-dunite interactions at 0.5 and 0.7 GPa: experimental constraints on the origin of olivine-rich troctolites. Lithos 323, 44–57. https://doi.org/10.1016/j.lithos.2018.09.022
Show in context
In the long duration runs (≥48 h), olivine has rather homogeneous major element compositions marked by higher CaO and lower NiO and XMg [XMg = Mg/(Mg + Fetot)] than the initial SC olivine (Fig. S-3), as observed in basalt-dunite reaction experiments (Borghini et al., 2018).
View in article
Borghini, G., Rampone, E., Zanetti, A., Class, C., Fumagalli, P., Godard, M. (2020) Ligurian pyroxenite-peridotite sequences (Italy) and the role of melt-rock reaction in creating enriched-MORB mantle sources. Chemical Geology 532, 119252. https://doi.org/10.1016/j.chemgeo.2019.07.027
Show in context
New clinopyroxenes show clockwise-rotated average REE patterns (Fig. 1f), very similar to REE patterns computed in studies that documented the effect of interaction between enriched melts and residual clinopyroxene within pyroxenite-bearing veined peridotite (Borghini et al., 2020), or during melt infiltration during open system mantle melting, to explain the trace element variability of abyssal peridotite (Brunelli et al., 2014).
View in article
Similar high LaN/SmN ratios have been documented in mantle peridotites inferred to be metasomatised by E-MORB-like melts coming from pyroxenitic veins (Northern Apennine veined mantle; Borghini et al., 2020).
View in article
Chondrite normalised (a) LaN/SmN versus YbN and (b) SmN/NdN versus LuN/HfN of initial, new and relict clinopyroxene from reacted and crystallisation experiments compared to data of clinopyroxenes in metasomatised peridotites from Northern Apennine veined mantle (black diamonds, Borghini et al., 2020).
View in article
Borghini, G., Rampone, E., Class, C., Goldstein, S., Cai, Y., Cipriani, A., Hofmann, A.W., Bolge, L. (2021) Enriched Hf–Nd isotopic signature of veined pyroxenite-infiltrated peridotite as a possible source for E-MORB. Chemical Geology 586, 120591. https://doi.org/10.1016/j.chemgeo.2021.120591
Show in context
Ancient events of melt infiltration in those peridotites modified the trace element composition of clinopyroxene by lowering SmN/NdN and LuN/HfN ratios that, over time, formed mantle domains with enriched Nd-Hf isotopic signatures (Borghini et al., 2021).
View in article
Brunelli, D., Paganelli, E., Seyler, M. (2014) Percolation of enriched melts during incremental open-system melting in the spinel field: A REE approach to abyssal peridotites from the Southwest Indian Ridge. Geochimica et Cosmochimica Acta 127, 190–203. https://doi.org/10.1016/j.gca.2013.11.040
Show in context
New clinopyroxenes show clockwise-rotated average REE patterns (Fig. 1f), very similar to REE patterns computed in studies that documented the effect of interaction between enriched melts and residual clinopyroxene within pyroxenite-bearing veined peridotite (Borghini et al., 2020), or during melt infiltration during open system mantle melting, to explain the trace element variability of abyssal peridotite (Brunelli et al., 2014).
View in article
In a scenario of multiple melt injections, porous migration of melts enriched in trace elements may efficiently refertilise mantle clinopyroxene (e.g., Brunelli et al., 2014).
View in article
Hart, S.R., Dunn, T. (1993) Experimental cpx/melt partitioning of 24 trace elements. Contributions to Mineralogy and Petrology 113, 1–8. https://doi.org/10.1007/BF00320827
Show in context
Using the REE concentrations measured in new clinopyroxenes and texturally associated glasses, we computed “reaction” cpx/melt distribution coefficients (Fig. 3a), which are comparable to those derived by equilibrium experiments (Hart and Dunn, 1993; Blundy et al., 1998; Lundstrom et al., 1998; Hill et al., 2000; McDade et al., 2003).
View in article
Hauri, E.H. (1997) Melt migration and mantle chromatography, 1: simplified theory and conditions for chemical and isotopic decoupling. Earth and Planetary Science Letters 153, 1–19. https://doi.org/10.1016/S0012-821X(97)00157-X
Show in context
Several numerical and theoretical studies investigated the role and kinetics of these grain-scale processes (e.g., Navon and Stolper, 1987; Hauri, 1997; Van Orman et al., 2002) and laboratory experiments successfully reproduced textural and chemical variations observed in natural mantle samples (e.g., Morgan and Liang, 2005; Van den Bleeken et al., 2010; Wang et al., 2020).
View in article
Hill, E., Wood, B.J., Blundy, J.D. (2000) The effect of Ca-Tschermaks component on trace element partitioning between clinopyroxene and silicate melt. Lithos 53, 203–215. https://doi.org/10.1016/S0024-4937(00)00025-6
Show in context
Using the REE concentrations measured in new clinopyroxenes and texturally associated glasses, we computed “reaction” cpx/melt distribution coefficients (Fig. 3a), which are comparable to those derived by equilibrium experiments (Hart and Dunn, 1993; Blundy et al., 1998; Lundstrom et al., 1998; Hill et al., 2000; McDade et al., 2003).
View in article
Lambart, S., Laporte, D., Schiano, P. (2009) An experimental study of focused magma transport and basalt–peridotite interactions beneath mid-ocean ridges: implications for the generation of primitive MORB compositions. Contributions to Mineralogy and Petrology 157, 429–451. https://doi.org/10.1007/s00410-008-0344-7
Show in context
Such a high melt/rock ratio is consistent with previous melt transport experiments (e.g., Lambart et al., 2009) or melt-peridotite interaction occurring in the host mantle of pyroxenite veins (Bodinier et al., 2004).
View in article
Liang, Y. (2003) Kinetics of crystal-melt reaction in partially molten silicates: 1. Grain scale processes. Geochemistry, Geophysics, Geosystems 4, 1045. https://doi.org/10.1029/2002GC000375
Show in context
The interaction between an infiltrating melt and partially molten peridotite is controlled by grain-scale processes that involve dissolution, precipitation, reprecipitation and diffusive exchange between the interstitial melt and surrounding crystals (Liang, 2003).
View in article
Theoretical studies revealed that REE fractionation via diffusion is rather sluggish during melt porous flow (e.g., Van Orman et al., 2002; Liang, 2003).
View in article
Lo Cascio, M., Liang, Y., Shimizu, N., Hess, P.C. (2008) An experimental study of the grain-scale processes of peridotite melting: implications for major and trace element distribution during equilibrium and disequilibrium melting. Contributions to Mineralogy and Petrology 156, 87–102. https://doi.org/10.1007/s00410-007-0275-8
Show in context
However, very few experimental studies have directly investigated the trace element (re-)distribution in mantle minerals resulting from melt-peridotite reaction (Lo Cascio et al., 2008; Yao et al., 2012; Ma and Shaw, 2021) which is mostly due to analytical difficulties in measuring trace element concentrations of fine-grained experimental phases.
View in article
REE diffusion within cpx relics coincides with dissolution and precipitation during the interaction with melts (Lo Cascio et al., 2008).
View in article
However, REE diffusion over a distance of less than 200 μm has been observed in reaction couple experiments (Lo Cascio et al., 2008).
View in article
Lundstrom, C.C., Shaw, H.F., Ryerson, F.J., Williams, Q., Gill, J. (1998) Crystal chemical control of clinopyroxene-melt partitioning in the Di-Ab-An system: implications for elemental fractionations in the depleted mantle. Geochimimica et Cosmochimica Acta 62, 2849–2862. https://doi.org/10.1016/S0016-7037(98)00197-5
Show in context
Using the REE concentrations measured in new clinopyroxenes and texturally associated glasses, we computed “reaction” cpx/melt distribution coefficients (Fig. 3a), which are comparable to those derived by equilibrium experiments (Hart and Dunn, 1993; Blundy et al., 1998; Lundstrom et al., 1998; Hill et al., 2000; McDade et al., 2003).
View in article
Ma, S., Shaw, C.S.J. (2021) An Experimental Study of Trace Element Partitioning between Peridotite Minerals and Alkaline Basaltic Melts at 1250°C and 1 GPa: Crystal and Melt Composition Impacts on Partition Coefficients. Journal of Petrology 62, egab084. https://doi.org/10.1093/petrology/egab084
Show in context
However, very few experimental studies have directly investigated the trace element (re-)distribution in mantle minerals resulting from melt-peridotite reaction (Lo Cascio et al., 2008; Yao et al., 2012; Ma and Shaw, 2021) which is mostly due to analytical difficulties in measuring trace element concentrations of fine-grained experimental phases.
View in article
McDade, P., Blundy, J.D., Wood, B.J. (2003) Trace element partitioning on the Tinaquillo Lherzolite solidus at 1.5 GPa. Physics of the Earth and Planetary Interiors 139, 129–147. https://doi.org/10.1016/S0031-9201(03)00149-3
Show in context
Using the REE concentrations measured in new clinopyroxenes and texturally associated glasses, we computed “reaction” cpx/melt distribution coefficients (Fig. 3a), which are comparable to those derived by equilibrium experiments (Hart and Dunn, 1993; Blundy et al., 1998; Lundstrom et al., 1998; Hill et al., 2000; McDade et al., 2003).
View in article
Morgan, Z., Liang, Y. (2005) An experimental study of the kinetics of lherzolite reactive dissolution with applications to melt channel formation. Contributions to Mineralogy and Petrology 150, 369–385. https://doi.org/10.1007/s00410-005-0033-8
Show in context
Several numerical and theoretical studies investigated the role and kinetics of these grain-scale processes (e.g., Navon and Stolper, 1987; Hauri, 1997; Van Orman et al., 2002) and laboratory experiments successfully reproduced textural and chemical variations observed in natural mantle samples (e.g., Morgan and Liang, 2005; Van den Bleeken et al., 2010; Wang et al., 2020).
View in article
Navon, O., Stolper, E. (1987) Geochemical Consequences of Melt Percolation: The Upper Mantle as a Chromatographic Column. The Journal of Geology 95, 285–307. https://doi.org/10.1086/629131
Show in context
Several numerical and theoretical studies investigated the role and kinetics of these grain-scale processes (e.g., Navon and Stolper, 1987; Hauri, 1997; Van Orman et al., 2002) and laboratory experiments successfully reproduced textural and chemical variations observed in natural mantle samples (e.g., Morgan and Liang, 2005; Van den Bleeken et al., 2010; Wang et al., 2020).
View in article
Several interactions with REE-depleted clinopyroxene are expected to progressively smooth the LREE-HREE fractionation of a single batch of transient melt, as found in reacted glasses of this study, confirming the important role of melt transport processes in the chemical variations of erupted basalts (Navon and Stolper, 1987).
View in article
Rampone, E., Borghini, G., Basch, V. (2020) Melt migration and melt-rock reaction in the Alpine-Apennine peridotites: Insights on mantle dynamics in extending lithosphere. Geoscience Frontiers 11, 151–166. https://doi.org/10.1016/j.gsf.2018.11.001
Show in context
Reaction between mantle minerals and transient melts may strongly affect the mineralogy and chemistry of the upper mantle (e.g., Rampone et al., 2020, and references therein).
View in article
Sun, C., Liang, Y. (2012) Distribution of REE between clinopyroxene and basaltic melt along a mantle adiabat: effects of major element composition, water, and temperature. Contributions to Mineralogy and Petrology 163, 807–823. https://doi.org/10.1007/s00410-011-0700-x
Show in context
These also closely overlap the equilibrium distribution coefficients measured for REE in our crystallisation run at 2 GPa and 1300 °C and those computed using parameterisation by Sun and Liang (2012) based on the composition of clinopyroxenes in our reaction experiments (Fig. 3b).
View in article
“Reaction” DREEcpx/melt from this study compared to (a) DREEcpx/melt derived by equilibrium crystallisation experiment at 2 GPa and 1300 °C and those from the literature (list of references is in the text), and (b) the DREEcpx/melt provided by the application of the parameterised lattice strain model by Sun and Liang (2012), to each reaction experiments of this study.
View in article
Van Den Bleeken, G., Müntener, O., Ulmer, P. (2010) Reaction Processes between Tholeiitic Melt and Residual Peridotite in the Uppermost Mantle: an Experimental Study at 0.8 GPa. Journal of Petrology 51, 153–183. https://doi.org/10.1093/petrology/egp066
Show in context
Several numerical and theoretical studies investigated the role and kinetics of these grain-scale processes (e.g., Navon and Stolper, 1987; Hauri, 1997; Van Orman et al., 2002) and laboratory experiments successfully reproduced textural and chemical variations observed in natural mantle samples (e.g., Morgan and Liang, 2005; Van den Bleeken et al., 2010; Wang et al., 2020).
View in article
Van Orman, J.A., Grove, T.L., Shimizu, N. (2001) Rare earth element diffusion in diopside: influence of temperature, pressure, and ionic radius, and an elastic model for diffusion in silicates. Contributions to Mineralogy and Petrology 141, 687–703. https://doi.org/10.1007/s004100100269
Show in context
These results indicate that rapid textural replacement of relict clinopyroxene strongly improves trace element remobilisation, even for LREE having low diffusion rate (Van Orman et al., 2001).
View in article
Van Orman, J.A., Grove, T.L., Shimizu, N. (2002) Diffusive fractionation of trace elements during production and transport of melt in Earth’s upper mantle. Earth and Planetary Science Letters 198, 93–112. https://doi.org/10.1016/S0012-821X(02)00492-2
Show in context
Several numerical and theoretical studies investigated the role and kinetics of these grain-scale processes (e.g., Navon and Stolper, 1987; Hauri, 1997; Van Orman et al., 2002) and laboratory experiments successfully reproduced textural and chemical variations observed in natural mantle samples (e.g., Morgan and Liang, 2005; Van den Bleeken et al., 2010; Wang et al., 2020).
View in article
Theoretical studies revealed that REE fractionation via diffusion is rather sluggish during melt porous flow (e.g., Van Orman et al., 2002; Liang, 2003).
View in article
Wang, C., Lo Cascio, M., Liang, Y., Xu, W. (2020) An experimental study of peridotite dissolution in eclogite-derived melts: Implications for styles of melt-rock interaction in lithospheric mantle beneath the North China Craton. Geochimica et Cosmochimica Acta 278, 157–176. https://doi.org/10.1016/j.gca.2019.09.022
Show in context
Several numerical and theoretical studies investigated the role and kinetics of these grain-scale processes (e.g., Navon and Stolper, 1987; Hauri, 1997; Van Orman et al., 2002) and laboratory experiments successfully reproduced textural and chemical variations observed in natural mantle samples (e.g., Morgan and Liang, 2005; Van den Bleeken et al., 2010; Wang et al., 2020).
View in article
Warren, J.M. (2016) Global variations in abyssal peridotite compositions. Lithos 248–251, 193–219. http://dx.doi.org/10.1016/j.lithos.2015.12.023
Show in context
Modal and chemical changes in mantle peridotite can occur as a result of diffuse porous flow, or by focused melt infiltration related to melt-bearing conduits (dunite channels), or pyroxenitic veins and layers (mantle re-fertilization; e.g., Warren, 2016).
View in article
Yao, L., Sun, C., Liang, Y. (2012) A parameterized model for REE distribution between low-Ca pyroxene and basaltic melts with applications to REE partitioning in low-Ca pyroxene along a mantle adiabat and during pyroxenite-derived melt and peridotite interaction. Contributions to Mineralogy and Petrology 164, 261–280. https://doi.org/10.1007/s00410-012-0737-5
Show in context
However, very few experimental studies have directly investigated the trace element (re-)distribution in mantle minerals resulting from melt-peridotite reaction (Lo Cascio et al., 2008; Yao et al., 2012; Ma and Shaw, 2021) which is mostly due to analytical difficulties in measuring trace element concentrations of fine-grained experimental phases.
View in article
top
Supplementary Information
The Supplementary Information includes:
Download Supplementary date file for Tables S-1 to S-10 (.xlsx)
Download the Supplementary Information (PDF)